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Does it have an anti glare coating? If it does, you will make it look worse if you try to polish it. If you want to try it any way, look for information on making lenses. You'll need to use a similar process. First you'll have to grind out the scratch, then polish it with finer and finer materials until it's smooth. It will be a LOT of work considering that nice CRT monitors literally litter the streets these days.
I've seen quite a few flat CRT monitors that actually have a sheet of tinted anti-glare plastic over the screen. This scratches very easily, but it can be peeled off. I've seen this on both Sony and Mitsubishi monitor CRTs. You'd have to pull the CRT to be sure though. You could probably replace it with car window tint if it leaves the screen looking too light.
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